My students and I are interested in the broad field of synthetic organic chemistry. Our three main areas of research include: 1) the synthesis of complex structures inspired by nature; 2) the application of transition metal catalysts to organic chemistry; and 3) the synthesis of organic polymers with photocleavable crosslinks.
Currently students are focused on developing air-stable (cyclopentadienone)iron di- and tricarbonyl compounds for use as reduction and oxidation catalysts. We have discoverd that these compounds catalyze a variety of oxidative and reductive transformations including alcohol oxidations, ketone and aldehyde reductions, oxidative cyclizations of diols, and selective epoxide ring-openings. Catalyst design is at the heart of our work, and we are constantly thriving to develop more active, air-stable iron catalysts. Additionally, we are interested in understanding the mechanism of these iron-catalyzed reactions to aid in further catalyst development.
RECENT PUBLICATIONS: (* denotes Gettysburg College undergraduate student)
4. *Plank, T. N.; *Drake, J. L.; *Kim, D. K.; Funk, T. W. "Air-Stable, Nitrile-Ligated (Cyclopentadienone)iron Dicarbonyl Compounds as Transfer Reduction and Oxidation Catalysts." Advanced Synthesis & Catalysis 2012, 354, 597-601.
3. *Ziegler, D. T.; *Steffens, A. M.; Funk, T. W. "Synthesis of alpha-Methyl Ketones by a Selective, Iridium-Catalyzed Cyclopropanol Ring-Opening Reaction." Tetrahedron Letters 2010, 51, 6726-6729.
2. *Moyer, S. A.; Funk, T. W. "Air-Stable Iron Catalyst for the Oppenauer-Type Oxidation of Alcohols." Tetrahedron Letters 2010, 51, 5430-5433.
1. Funk, T. W. "Enantioselective Synthesis of 5-epi-Citreoviral Using Ruthenium-Catalyzed Asymmetric Ring-Closing Metathesis." Organic Letters 2009, 11, 4998-5001.